Fri 13 Jun 2008, 09:09 GMT

Nanotech paper sops up bunker spills


Scientists develop groundbreaking nanowire mesh that can absorb up to 20 times its weight in oil.



A mat of nanowires with the touch and feel of paper could be an important new tool in the cleanup of bunker spills according to the latest research carried out by a group of US scientists.

Researchers at the Massachusetts Institute of Technology say they have created a membrane that can absorb up to 20 times its weight in oil, and can be recycled many times for future use. The oil itself can also be recovered. Some 200,000 tons of oil have already been spilled at sea since the start of the decade.

"What we found is that we can make 'paper' from an interwoven mesh of nanowires that is able to selectively absorb hydrophobic liquids - oil-like liquids - from water," said Francesco Stellacci, an associate professor in the Department of Materials Science and Engineering and leader of the work.

Stellacci explained that there are other materials that can absorb oils from water, "but their selectivity is not as high as ours." In other words, conventional materials still absorb some water, making them less efficient at capturing the contaminant.

The new material appears to be completely impervious to water. "Our material can be left in water a month or two, and when you take it out it's still dry," Stellacci said. "But at the same time, if that water contains some hydrophobic contaminants, they will get absorbed."

Made of potassium manganese oxide, the nanowires are stable at high temperatures. As a result, oil within a loaded membrane can be removed by heating above the boiling point of oil. The oil evaporates, and can be condensed back into a liquid. The membrane - and oil - can be used again.

Two key properties make the system work. First, the nanowires form a spaghetti-like mat with many tiny pores that make for good capillarity, or the ability to absorb liquids. Second, a water-repelling coating keeps water from penetrating into the membrane. Oil, however, isn't affected, and seeps into the membrane.

The membrane is created by the same general technique as its low-tech cousin, paper. "We make a suspension of nanowires, like a suspension of cellulose [the key component of paper], dry it on a non-sticking plate, and we get pretty much the same results," Stellacci said.

In a commentary accompanying the scientists' report published in Nature Nanotechnology, Joerg Lahann of the University of Michigan concluded: "Stellacci and co-workers have provided an example of a nanomaterial that has been rationally designed to address a major environmental challenge."


Jurgen Gerdes, WinGD. WinGD signs global service agreement for TMS Cardiff Gas LNG carrier newbuilds  

WinGD will support six dual-fuel engines on three new LNG carriers for the Athens-based operator throughout their operational lives.

Yangze LNG 01 vessel. Yangzijiang Xinfu delivers first 175,000-cbm LNG carrier built by Chinese private shipyard  

Vessel features two dual-fuel MAN B&W 5G70ME-C10.5-GA-EGR engines fitted with cryogenic units.

Kaguya 200th ship-to-ship (STS) LNG bunkering operation. LNG bunkering vessel Kaguya completes 200th ship-to-ship operation in Japan  

K Line’s joint venture vessel reaches milestone in Mikawa Bay.

MFM Nicole vessel. Synergy Marine adds dual-fuel LPG carrier to managed fleet  

MFM Nicole joins Synergy’s gas carrier portfolio as owners weigh fuel choices ahead of MEPC 85 negotiations.

CMA CGM Notre Dame vessel. DSV to use CMA CGM’s ACT+ solution to slash shipping emissions  

Danish firm targets 12,000-tonne reduction in CO₂ emissions over two years through the use of UCOME-based biofuels.

Peninsula 2026 graduate cohort. Peninsula welcomes 2026 graduate cohort across global bunkering network  

Bunker firm brings new graduates into roles spanning Houston, Singapore, Gibraltar, Monaco and Las Palmas.

Mathias Krogsgard, Malik Supply. Malik Supply appoints Mathias Krogsgård as bunker trader  

Danish bunker firm adds trader with export and technology background to growing team.

Jeroen De Vos, Peninsula. Biofuel adoption in shipping shifts from debate to delivery, says Peninsula's Jeroen de Vos  

Marine biofuels have moved from pilot projects to routine fuel strategy, argues IBIA vice-chair.

KEPCO E&C and KR signing. KEPCO E&C and Korean Register of Shipping to collaborate on marine SMR development  

Korean firms to develop technical standards and certification pathways for the BANDI offshore small modular reactor.

Ship-to-ship (STS) LNG bunkering operation at the Port of Sagunto. Peninsula completes first LNG bunkering operation at Sagunto  

Levante LNG bunkering vessel supplies K Line car carrier in landmark delivery.